Changing Your Working Directory
When you start a dialogue box to open or save a document, LibreOffice initially displays your working directory. To change this directory:
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Choose LibreOffice - PreferencesTools - Options - LibreOffice - Paths.
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Click My Documents and click the Edit button, or double-click on My Documents.
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In the Select Path dialogue box, choose the working directory you want and click Select.
You also use this procedure to change the directory displayed by LibreOffice when you want to insert a graphic. Choose LibreOffice - PreferencesTools - Options - LibreOffice - Paths - Images, then follow step 3.